Michel Orrit

Optical microscopy and spectroscopy of single molecules and single plasmonic gold nanoparticles 

Optical signals provide unique insights into the dynamics of nano-objects and their surroundings [1]. I shall present some of our experiments of the last few years.

i) We study single gold nanoparticles by photothermal and pump-probe microscopy. We recently studied the dynamics of vapor nanobubbles created in the liquid surrounding a single immobilized gold nanosphere. We found that these nanobubbles form in an instable, explosive process before collapsing. Nanobubbles can react to reflected sound waves such as those released in the explosion [2].

ii) Photothermal microscopy opens the study of non-fluorescent absorbers, down to single-molecule sensitivity [3]. Combining this contrast with photoluminescence, we can measure the luminescence quantum yield on a single-particle basis. The high signal-to-noise ratio of this technique enables uses of individual gold nanoparticles for local plasmonic and chemical probing [4] (see Fig. 1).

 iii) Gold nanorods generate strong field enhancements near their tips. Matching the rods’ plasmon to a dye’s spectra, we observe enhancements in excess of thousand-fold for the fluorescence of single Crystal Violet molecules [5]. This method generalizes single-molecule fluorescence to a broad range of weak emitters.

[1] F. Kulzer et al., Angew. Chem. Int. Ed. 49 (2010) 854.

[2] L. Hou et al., New J. Phys., in press (2015)

[3] A. Gaiduk et al. Science 330 (2010) 353

[4] P. Zijlstra et al., Nature Nanotech. 7 (2012) 379.

[5] H. Yuan et al., Angew. Chem. Int. Ed. 52 (2013) 1217-1221